Mechanistic Switch Leading to Highly Efficient Chirality Transfer in Pd (0)-Catalyzed Coupling-Cyclization of Aryl Iodides with 1:1 Acid-Base Salts of 2, 3-Allenoic Acids and l-(-) -Cinchonidine or d-(+)-/l-(-)-a-Methylbenzylamine. Enantioselective Synthesis of Highly Optically Active 3-Aryl Polysubstituted Butenolides
Mechanistic Switch Leading to Highly Efficient Chirality Transfer in Pd (0)-Catalyzed Coupling-Cyclization of Aryl Iodides with 1:1 Acid-Base Salts of 2, 3-Allenoic Acids and l-(-) -Cinchonidine or d-(+)-/l-(-)-a-Methylbenzylamine. Enantioselective Synthesis of Highly Optically Active 3-Aryl Polysubstituted Butenolides